I was looking for the ingredients in Clorox Clean Up with bleach Spray

I like the way it cleans, but wonder whether or not there are any glycol ethers or butylated ingredients (What is glycol ether?) link

It appears so  *

Usable glycol ethers include propylene glycol methyl ether (CAS No. 107-98-2), dipropylene glycol methyl ether (CAS No. 34590-94-8), ethylene glycol n-butyl ether MSDS (CAS No. 111-76-2), and propylene glycol t-butyl ether

(CAS No. 57018-52-7), which is the most preferred supplemental solvent for use in the practice of the present invention.

 

Names (NTP) synonyms for propylene glycol t-butyl ether

  • PGTBE
  • Propylene glycol mono-t-butyl ether
  • 1-(1,1-DIMETHYLETHOXY)-2-PROPANOL (9CI)
  • TERT-BUTOXYPROPANOL
  • PROPYLENE GLYCOL T-BUTYL ETHER
  • PGMBE
USES: Industrial solvent... And in commercial cleaners, inks, adhesives, nail polish, lacquers, latex paints, and other coatings. It has  properties that permit its use as a substitute for ethylene glycol butyl ether.
But not by the MSDS provided by Clorox Company  pdf
 
 

They don't have to disclose them, though, per current laws, right?

  • Clorox Clean Up Cleaner with Bleach
  • Clorox Clean Up Cleaner with Bleach-04/01/2002 & Gels
  • Clorox Clean Up Spray with Bleach
  • Clorox Clean Up Spray with Bleach-04/01/2002
      Clorox Clean Up Cleaner with Bleach-04/01/2002
    Handling: From MSDS
    Hygienic Practices: Do not get in eyes or on clothing. Avoid prolonged or repeated skin contact. Avoid prolonged breathing of vapor. Use only in well- ventilated areas.
    Personal Protection: Wear safety glasses. For sensitive skin or repeated/prolonged use, wear gloves.
    Ventilation: Use general ventilation to minimize exposure to gases or aerosols associated with this product.
     
    Ingredients from MSDS/Label
    Chemical CAS No / Unique ID Percent
    Sodium hydroxide 001310-73-2 0.5-2
    Sodium hypochlorite 007681-52-9 1-5
       
    EPA Registration Code: 5813-21 (So is a pesticide a component?)

    Butylated Glycol Ether:  A memory loss causing chemical  *

    1. Testing Status: Propylene glycol mono-t-butyl ether M90029 ...

      Citation: Toxicology and Carcinogenesis Studies of Propylene Glycol Mono-t-Butyl Ether (Cas No. 57018-52-7) in F344/N Rats and B6C3F1 Mice and a Toxicology ...

    Why doesn't the USA know that glycol ethers cause cancers * *, autoimmune issues * and birth defects?

    What would be necessary to change the laws so that these are disclosed in home cleaning products, too

    Pres Obama believes in prevention of harm

ALL INFORMATION, DATA, AND MATERIAL CONTAINED, PRESENTED, OR PROVIDED HERE VIA INTERNET COMMUNICATION IS FOR GENERAL INFORMATION PURPOSES ONLY AND IS NOT TO BE CONSTRUED OR INTENDED AS PROVIDING MEDICAL OR LEGAL ADVICE.

 

US Patent 5705470 - Sprayable cleaning gel, dispenser, and method of using same

US Patent Issued on January 6, 1998
Estimated Patent Expiration Date: December 15, 2015

http://www.patentstorm.us/patents/5705470/claims.html   back up copy as follows

5705470 Sprayable cleaning gel, dispenser, and method of using same
A substantially homogeneous sprayable cleaning gel composition which is substantially free of suspended encapsulated particles exhibits extended dwell time when sprayed on to a surface as compared to a low viscosity spray cleaner. The extended dwell time ...

A cleaning and bleaching gel has recently come on to the market, sold by the CLOROX Company under the name "CLOROX Clean-up Gel". No spray applicator is advertised for use with this product, and the bleach component of the product is emphasized in the advertisements. This product contains a significant quantity of bleach and the label warns not to use it on clothes, fabric, carpet, wood, and painted surfaces, and further warns that prolonged contact with metal, old porcelain or plastic laminate countertops may cause discoloration. Applications available for this bleaching product, because of the manufacturer's warnings and limitations, are necessarily somewhat limited.

Products known generally as `naval jelly`, which are applied with a brush, are known and used for cleaning rust off of metals such as steel. However, these products are caustic to exposed skin, give off hazardous fumes, may be flammable, and are not suitable for cleaning household surfaces. Moreover, naval jelly is made up of entirely different components from those that make up the sprayable cleaning gel composition according to the present invention.
 

Claims

What is claimed is:

1. A sprayable cleaning gel composition which is free of suspended encapsulated particles, consisting essentially of:

from about 75% to about 98% by weight of a liquid carrier;

from about 0.005% to about 20% by weight of a surfactant component comprising at least one surfactant selected from the group consisting of nonionic, anionic, cationic, amphoteric, and zwitterionic surfactants and mixtures thereof;

from about 0.001% to about 5% by weight of a carboxylic acid copolymer dispersant;

from about 0.01% to about 2% by weight of a high molecular weight powdered, crosslinked polyacrylic acid thickener;

from about 1% to about 20% by weight of at least one supplemental solvent for dissolving oil-based particles in water, said at least one supplemental solvent being selected from the group consisting of:

ethylene glycol ethers; and

propylene glycol ethers; and

from about 0.05% to about 1.0% by weight of a nonionic ester complex anti-static agent;

wherein said sprayable cleaning gel composition has a gel consistency having a viscosity ranging from about 900 centipoise to about 5,500 centipoise.

2. The composition of claim 1, wherein said surfactant is a nonionic surfactant.

3. The composition of claim 1, wherein said surfactant is a nonionic water-soluble lubricant and softener which provides both surfactant and anti-static properties to the composition in a range from about 0.05% to about 1.0% of the composition.

4. The composition of claim 1, wherein said viscosity range is from about 1,500 centipoise to about 4,500 centipoise.

5. A packaged cleaning gel composition for cleaning surfaces, comprising:

a sprayable cleaning gel composition which is free of suspended encapsulated particles, consisting essentially of:

from about 75% to about 98% by weight of a liquid carrier;

from about 0.005% to about 10% by weight of a surfactant component comprising at least one surfactant selected from the group consisting of nonionic, anionic, cationic, amphoteric, and zwitterionic surfactants and mixtures of the above;

from about 0.001% to about 5% by weight of a carboxylic acid copolymer dispersant;

from about 0.01% to about 2% by weight of a high molecular weight powdered, crosslinked polyacrylic acid thickener;

from about 1% to about 20% by weight of at least one supplemental solvent for dissolving oil-based particles in water, said supplemental solvent selected from the group consisting of:

ethylene glycol ethers; and

propylene glycol ethers; and

from about 0.05% to about 1.0% by weight of a nonionic ester complex anti-static agent;

wherein said sprayable cleaning gel composition has a gel consistency having viscosity ranging from about 900 centipoise to about 5,500 centipoise; and

a spray applicator comprising:

a container having a reservoir for holding said sprayable cleaning gel composition therewithin;

a spray head movably connected with said container, said spray head having an orifice therein, said reservoir being in fluid communication with said spray head and said orifice when said spray head is selectively moved in relation to said container, and

means for propelling said sprayable cleaning gel composition sprayably through said orifice responsively to said selective movement of said spray head.

6. The packaged cleaning gel composition of claim 5, wherein said orifice in said spray head has a diameter range from about 0.010 to about 0.040 inch.

7. The packaged cleaning gel composition of claim 6, wherein said surfactant is a nonionic water-soluble lubricant and softener which provides both surfactant and anti-static properties to the composition in a range from about 0.05% to about 1.0% of the composition.

8. A method for cleaning a surface, comprising the steps of:

spraying a sprayable cleaning gel composition which is free of suspended encapsulated particles, consisting essentially of:

from about 75% to about 98% by weight of a liquid carrier;

from about 0.005% to about 20% by weight of a surfactant component comprising at least one surfactant selected from the group consisting of nonionic, anionic, cationic, amphoteric, and zwitterionic surfactants and mixtures thereof;

from about 0.001% to about 5% by weight of a carboxylic acid copolymer dispersant;

from about 0.01% to about 2% by weight of a high molecular weight powdered, crosslinked polyacrylic acid thickener;

from about 1% to about 20% by weight of at least one supplemental solvent for dissolving oil-based particles in water, said at least one supplemental solvent being selected from the group consisting of:

ethylene glycol ethers; and

propylene glycol ethers; and

from about 0.05% to about 1.0% by weight of a nonionic ester complex anti-static agent; having a viscosity from about 900 centipoise to about 5,550 centipoise onto a surface to be cleaned, wherein said sprayable cleaning gel composition clings to and dwells on said surface rather than running downwardly thereon due to gravity at standard temperature and pressure;

spreading said sprayable cleaning gel composition selectively around said surface with a wiping article; and

wiping said sprayable cleaning gel composition off said surface via the wiping article to thereby clean the surface.

9. The method of claim 8, wherein said step of wiping reduces static electricity on the surface. which is free of suspended encapsulated particles, consisting essentially of:

from about 75% to about 98% by weight of a liquid carrier;

from about 0.005% to about 20% by weight of a surfactant component comprising at least one surfactant selected from the group consisting of nonionic, anionic, cationic, amphoteric, and zwitterionic surfactants and mixtures thereof;

from about 0.001% to about 5% by weight of a carboxylic acid copolymer dispersant;

from about 0.01% to about 2% by weight of a high molecular weight powdered, crosslinked polyacrylic acid thickener;

from about 1% to about 20% by weight of at least one supplemental solvent for dissolving oil-based particles in water, said at least one supplemental solvent being selected from the group consisting of:

ethylene glycol ethers; and

propylene glycol ethers; and from about 0.05 to about 1.0% by weight of a nonionic ester complex anti-static agent.

 

Other References

  • Research Disclosure 382042, No. 382 Feb. 1996
  • Clorox Clean-Up gel cleaner with bleach product advertisement of The Clorox Co., El Paso TX 88588, Detroit free Press, Aug. 12, 1995
  • Research Disclosure 382042, No. 382 Feb. 1996
  • Clorox Clean-Up gel cleaner with bleach product advertisement of The Clorox Co., El Paso TX 88588, Detroit free Press, Aug. 12, 1995
  • Lysol Cling thick liquid toilet bowl cleaner product advertisement of Reckitt & Colman, Del Rio, TX 78840, Detroit Free Press, Oct. 1, 1995
  • Soft Scrub liquid gel with bleach cleaner product advertisement of The Clorox Co., El Paso TX 88588, Detroit Free Press, Oct. 1, 1995
  • Eccolube RT-5-8 Technical Bulletin and Material Safety Data Sheet of Eastern Color & Chemical Co., Providence, RI 02904, dated Mar. 28, 1994
  • Eccostat 501 Technical Bulletin and Material Safety Data Sheet of Eastern Color & Chemical Co., Providence, RI 02904, date unknown
  • Carbopol product bulletin DET-300 for hard surface sprayable cleaner of 200cP, B.F. Goodrich Specialty Chemicals, Cleveland, OH 44141, dated Jun. 1995 or Apr. 1995
  • Carbopol product bulletin TDS-209 for sprayable cleaner of 90cP, B.F. Goodrich Specialty Chemicals, Cleveland, OH 44141, dated Mar., 1994, copyright 1993
  • Formulation Ideas in Soap/Cosmetics/Chemical Specialties, Sep. 1995, p. 127
  • Carbopol (registered TM) product use bulletin for thickening organic acids, B.F. Goodrich Specialty Chemicals, Cleveland, OH 44141, date unknown
  • Carbopol (registered TM) product bulletin TDS#203 for EZ-1 polymer, B.F. Goodrich Specialty Chemicals, Cleveland, OH 44141, 3 pages dated Sep. 1994
  • Carbopol (registered TM) product bulletins F001 through F0010 for various polishes, B.F. Goodrich Specialty Chemicals, Cleveland, OH 44141, dated Sep. 1994
  • Carbopol (registered TM) product bulletin PS-101 for powdered resins, B.F. Goodrich Specialty Chemicals, Cleveland, OH 44141, dated Nov. 1994
  • Buro Thix PCS product bulletin for thickener for FB-sodium percarbonate, Burlington Chemical Co., Inc., Burlington, NC 27216, dated 1987
  • Antifog Window Cleaner product bulletin, Burlington Chemical Co., Inc., Burlington, NC 27216, dated 1987
  • Formulary reference guide of Exxon Chemical Co., Tomah Products, Inc., Milton, WI 53563, data sheet P-5 describing vehicle cleaners, dated Aug. 1986
  • Glass Cleaner Formulas G-100, G-101, G-102 of Tomah Products, Inc., Milton, WI 53563, date unknown
  • Fact Sheet of Viscous Cleaners Formula A-104 and A-107 of Tomah Products, Inc., Milton, WI 53563, date unknown
  • Neodol Formulary for window/glass cleaners of Shell Chemical Co., Anaheim, CA 92803, dated Mar. 1988
  • Hard Surface Cleaners fact sheet of hard surface cleaners 25 through 28, of The Dow Chemical Co., Midland, MI 48674, dated May, 1991
  • All-Purpose Cleansers fact sheet of all-purpose cleaners 8 through 11, of The Dow Chemical Co., Midland, MI 48674, dated May, 1991
  • Glass Cleaners fact sheet of all-purpose cleaners 1 through 4, of The Dow Chemical Co., Midland, MI 48674, dated May, 1991
  • Sanitary Chemicals Manual, p. 56, of Rohm and Haas Co., Philadelphia, PA 19106, dated Aug. 197
Also in this?
Clorox Disinfecting Wipes-Fresh Scent (35 Wipes)
Ingredients from MSDS/Label
Chemical CAS No / Unique ID Percent
n-Alkyl(C14, 60%; C16, 30%; C12, 5%; C18, 5%) dimethylbenzyl ammonium chloride 000000-55-9 0.145
n-Alkyl(C12, 68%, C14, 32%) dimethyl ethylbenzyl ammonium chloride 000000-56-0 0.145
Isopropanol 000067-63-0 1-5

label all areas where 2-butoxyethanol compounds are stored... with POISON cautions

2-butoxyethanol is a primary cancer causing - autoimmune causing chemical

(exposure looks like 'the flu')

... a teratogen, an organic solvent, a neurotoxin, a pesticide, a poison

(Symptoms look like CFIDS, CFS, FM)

Do no Harm *

Be Careful what you clean with - What about Hydrogen Peroxide?   Earth Scrub?  *
http://www.valdezlink.com/re/msn/clean/menu.htm
Be careful what cleaning products around pets
http://www.valdezlink.com/re/msn/ourpets/menu.htm

The more you check into it, there are many cleaning products that have the glycol ether / not disclosed  *

7-9-09

Copyright © 2002 - 2009 Margaret Diann Hursh

except for any previously copyrighted material - Fair Use