BioGroup: Organic fertilizer:Reply -Reply

 
 


Subject: Fw: 8-97 acknowledges all 4 ingredients of inipol EAP 22 - except there is no sodium in the tri(laureth-4)phosphate *

inipol called surfactant


  • To: Multiple recipients of list bioremediation

  • Subject: BioGroup: Organic fertilizer: Reply -Reply

  • From: ALBERT VENOSA

  • Date: Fri, 22 Aug 1997 14:44:14 -0400

  •  


I've been following the thread about organic fertilizer,
and I would like to offer a few simple thoughts. First,
Inipol is a emulsion that contains urea as the nitrogen
form, sodium laureth phosphate as the phosphorus
source, oleic acid as an organic carrier, and the
surfactant 2-butoxyethanol. The nitrogen form, urea, is
not "organic" in the strict sense of the word. When it is
added to the environment, microorganisms catalyze
the breakdown of urea into ammonium and carbon
dioxide. So, the real nitrogen form is inorganic
ammonium. When Inipol directly contacts water, urea
is released almost immediately as the emulsion breaks
down. So, what you have in an oiled shoreline
situation that has been treated with Inipol is an
environment that contains released forms of
ammonium, oleic acid (which is a fatty acid, not a
hydrocarbon), an organic form of phosphorus, and a
little 2-butoxyethanol. The oleic acid enriches for the
growth of alkane degraders, not necessarily PAH
degraders. Thus, inorganic fertilizer should
theoretically work to stimulate oil degraders just as
well if not better than Inipol, since metabolic energy is
not wasted degrading the oleic acid prior to the
biodegradation of the hydrocarbons and PAH
degraders would not be masked by the huge increase
in oleic acid degraders followed by alkane degraders.
Of course, one must also account for the large
increase in the BOD caused by the extra carbon from
the oleic acid. 
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For soil applications, the highly viscous Inipol must be
able to penetrate the soil deeply enough to reach the
contamination. Depending on the hydraulic
conductivity of the particular soil being treated, it is
doubtful that Inipol would penetrate deeply enough to
be a real benefit as an in-situ application technique.
Albert D. Venosa, Ph.D.
U.S. Environmental Protection Agency
26 W. Martin Luther King Drive
Cincinnati, OH 45268
tel: 513-569-7668
fax: 513-569-7105

email: venosa.albert@epamail.epa.gov

 

Interesting to note that all ingredients were known to this EPA worker.

Lay comment/opinion:  I would not consider 12% by weight of the poison, 2-butoxyethanol to be 'a little.'  I would consider that to be a lot!  Especially when the poisonous ingredient of a pesticide may only be 1% of that product.

 
 
 
Sent: Thursday, September 11, 2003 7:08 AM
Subject: Do you feel the same way about Inipol EAP 22?

Dear Dr. Albert Venosa:
 
What was your role in the development of experimental chemicals used during the Exxon Valdez oil spill cleanup in 1989?
 
Have you seen this new scientific study?
  • It indicates that at 10 degrees C - NO bacterial anything is happening as relating to breaking down hydrocarbons.
  • What do you think the temperatures are in Alaska's water?
 
Apparently, in a pristine environment, close to 30% of the natural yeast
could degrade petroleum and some of them at very low temperatures, WHILE ZERO BACTERIA COULD DO THIS. 
 
I read one of your comments on Inipol EAP 22
& I question your belief that 'a little' 2-butoxyethanol was used.
Isn't 12% by weight more than just a 'little"?  How much is that by volume?
 
When the true toll is revealed of what happened
when EPA approved those experimental chemicals of the Exxon Valdez oil spill cleanup,
  • you will be amazed at how much human life was senselessly lost. 
  • You will be amazed at how the tragedy goes on.
I don't think either Inipol EAP 22
or any Corexit such as 9527 should be on your OK to use list.
 
I thought EPA was supposed to help us, not harm us;  
EPA made a very big mistake to say OK to chemical experiments.
 
Didn't anyone but Exxon follow up on what happened to the workers?
They're not even telling them what the medical info was.... not even when ordered by the court,

 

So something is REALLY wrong.
 
 
Margaret Hursh
PO Box 233
Valdez, Alaska 99686
 
I used to follow these:
 
  • To: Multiple recipients of list bioremediation

  • Subject: BioGroup: Organic fertilizer: Reply -Reply

  • From: ALBERT VENOSA

  • Date: Fri, 22 Aug 1997 14:44:14 -0400


I've been following the thread about organic fertilizer,
and I would like to offer a few simple thoughts. First,
Inipol is a emulsion that contains urea as the nitrogen
form, sodium laureth phosphate as the phosphorus
source, oleic acid as an organic carrier, and the
surfactant 2-butoxyethanol. The nitrogen form, urea, is
not "organic" in the strict sense of the word. When it is
added to the environment, microorganisms catalyze
the breakdown of urea into ammonium and carbon
dioxide. So, the real nitrogen form is inorganic
ammonium. When Inipol directly contacts water, urea
is released almost immediately as the emulsion breaks
down. So, what you have in an oiled shoreline
situation that has been treated with Inipol is an
environment that contains released forms of
ammonium, oleic acid (which is a fatty acid, not a
hydrocarbon), an organic form of phosphorus, and a
little 2-butoxyethanol. The oleic acid enriches for the
growth of alkane degraders, not necessarily PAH
degraders. Thus, inorganic fertilizer should
theoretically work to stimulate oil degraders just as
well if not better than Inipol, since metabolic energy is
not wasted degrading the oleic acid prior to the
biodegradation of the hydrocarbons and PAH
degraders would not be masked by the huge increase
in oleic acid degraders followed by alkane degraders.
Of course, one must also account for the large
increase in the BOD caused by the extra carbon from
the oleic acid. 
For soil applications, the highly viscous Inipol must be
able to penetrate the soil deeply enough to reach the
contamination. Depending on the hydraulic
conductivity of the particular soil being treated, it is
doubtful that Inipol would penetrate deeply enough to
be a real benefit as an in-situ application technique.

Photo Story

What Exxon Says

Yes, it was an experiment!

Personal Protective Equipment should have been Level IV - Not Class B

Does the military use Corexit 9527?

What Now?       Find the Workers!

9-11-03 summary of EVOS web pages