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....says one:
I am very sorry about what's happened in the
Exxon Valdez case and I am
very concerned about the actual incident at the Spanish coast.
I am just a 'researcher' dealing with surfactants etc.
not
associated with a big company.
For a period of years I dealt with the topic of
soil clean-up.
Some points to note (making nothing better)
There should have been stringent safety rules during the
'Exxon Valdez'
clean-up (protective gloves, inhalation protection, protected
'clean' areas
for having a break etc.)
The solvent butoxyethanol, also used in paints, as known,
requires safety
measures, however, there is no more concern, than in case of
aromatic
solvents, which are also contained in the crude oil. Important
to note,
that butoxyethanol facilitates the take-up of toxic components
of the
crude oil through the unprotected skin.
Nevertheless toxic solvents like butoxyethanol may be
substituted by
'harmless alternatives'. But one has to keep in mind that
together with the
crude oil this also will have the effect of enhanced take-up
through the
unprotected skin.
I hope, I did not bored you with this background.
Best wishes
T. Sobisch
...elaborate?
I can 'elaborate it
a little'. However, I am not able to work out an
expert's report on this matter. As you know the crude oil is a
very sticky
material. (As stated the toxicity reduces during weathering of
the oil due
to evaporation of toxic compounds, which otherwise may be
inhaled, it
becomes even more sticky when fluid compounds evaporate).
Due to the action of butoxyethanol the oil
becomes more fluid
and diffusion of toxic compounds is
enhanced.
Generally speaking all measures to enhance
the bioavailability
(to stimulate degradation)
will also enhance the bioavailability to
humans.
from... T. Sobisch
____________________________________________________________________
...
recently our paper Two-step bioreactor process for removal of
contaminants
with low bioavailability was published on-line at the
preprint server of
chemweb.com - <http://preprint.chemweb.com/envchem/0206002>,
which may be of
interest . . .
The paper is freely available after registration (only
password required).
We would be very interested in feedback and helpful
discussions.
Sincerely,
T. Sobisch
www.marquiswhoswho.net/SOBISCH/
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